Ana Karina Bortoni Dias will head the board of directors at the mid-sized bank.
Claudia Cooper, a former banker and finance minister, will become president of the Lima stock exchange.
The bank is currently running a pilot program and the launch will take place in May.
US authorities have placed sanctions on two shipping firms and identified 35 vessels as blocked property, as the World Bank says it is working on a social aid package for troubled Venezuela.
The funding will go to the trust fund established for the six PPP highways on which construction started last year, and the operation will be led by IDB Invest.
Chilean authorities, to help spur competition, are ending Transbank's monopoly, an announcement viewed in a positive light by the bank-owned company and banks themselves.